K |
Use (D denotes equillibrium) |
Name |
Equation |
In General |
Units/Assume |
Other |
Kc |
H2(g) +
I2(g) D 2HI(g) |
Equilibrium Constant |
Kc = [HI]2 |
Kc = [products]Pmoles |
No units in this case |
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[H2][
[I2] |
[reactants]Rmoles |
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Kc |
3In2(aq)
D 6In(aq) |
Equilibrium Constant |
Kc = [In(aq)]6 |
Units are |
Units = mol3 dm-9 |
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. [In2(aq)]3 |
(mol dm-3)(pmoles/rmoles) |
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Kc |
resin-H+(s) + Na+ D resin-Na+(s) + H+(aq) |
Partition Coefficient |
Kc =
[CO2(aq)] |
Kc = [solvent B] |
No units in this case |
Pressure->shift to |
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CO2(g) D CO2(aq) |
(special case of Kc) |
Pressure of CO2(g) |
[solvent A] |
Equation not required |
RHS, Kc increase |
Kow |
NH3(aq) D NH3(CHCl3) |
(special case of |
Kc = [NH3(CHCl3)] |
Kow = [in organic solvent] |
No units in this case |
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partiton coefficient) |
[NH3(aq)] |
[in water] |
Assume: excess solvent |
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Ksp |
CaCO3(s)
D Ca2+(aq) + CO32-(aq) |
Solubility Product |
Ksp = [Ca2+(aq)][CO32-(aq)] |
Ksp = [anion]max[cation]max |
Units = mol2 dm-6 |
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Units= mol2dm-6 (normally) |
Assume: excess solid |
[Ca2+]=[CO32-] |
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Ka |
CH3COOH(aq)
D CH3COO-(aq) + H+(aq) |
Acid Dissociation |
Ka = [H+(aq)] [CH3COO-(aq)] |
Ka = [H+(aq)] [A-(aq)] |
Units = mol dm-3 |
or Ka
=[H+(aq)] x [salt] |
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ethanoic acid (weak acid HA) D sodium ethanoate (salt A-) + H+ |
Constant |
[CH3COOH(aq)] |
[HA(aq)] |
Assume: excess A- (from salt), [HA] constant |
[acid] .[H+] constant |
Kw |
H2O(l) D H+(aq) + OH-(aq) |
Ionic Product of water |
Ka = [H+(aq)] [OH-(aq)] |
Simplified to [H+(aq)]2 |
Assume: excess water |
@298K, Kw = 10-14 |
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or 2H2O(l)
D H+(aq) + OH-(aq) |
(special case of Ka) |
[H2O(l)] |
([H+] =
[OH-] = 10-7mol dm-3) |
Note pH= -log[H+]= -log Ö(Kw) |
= 7 |
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